Who invented nitrogen




















Yet the subject could hardly be of greater importance, for the gathering on 11 November will focus on the centenary of an industrial process that has transformed our planet and threatens to bring even greater, more dramatic changes over the next years. The ammonia process — which uses nitrogen from the atmosphere as its key ingredient — was invented by German chemist Fritz Haber to solve a problem that faced farmers across the globe.

By the early 20th century they were running out of natural fertilisers for their crops. The Haber plant at Ludwigshafen, run by the chemical giant BASF, transformed that grim picture exactly years ago — by churning out ammonia in industrial quantities for the first time, triggering a green revolution. Several billion people are alive today only because Haber found a way to turn atmospheric nitrogen into ammonia fertiliser. But there is another, far darker side to the history of the Haber process.

By providing Germany with an industrial source of ammonia, the country was able to extend its fight in the first world war by more than a year, it is estimated. Britain's sea blockade would have ensured Germany quickly ran out of natural fertilisers for its crops. In addition, Germany would also have run out of nitrogen compounds, such as saltpetre, for its explosives. The Haber process met both demands. Trains, bursting with Haber-based explosives and scrawled with "Death to the French", were soon chugging to the front, lengthening the war and Europe's suffering.

Without it, there would have been no food for them. On the other hand, there are all the environmental impacts that a soaring world population, sustained by Haber fertilisers, have had. More than years ago, a scientific debate was raging in Europe over the importance of N for the growth of plants. British scientists Bennet Lawes and Joseph Henry Gilbert settled the debate when they published research showing that the addition of N fertilizers increased wheat yields in England.

Fifty years later, industrialized nations were challenged with how to feed their growing populations and Great Britain was importing the majority of its wheat. In , William Crooks, president for the British Association for the Advancement of Science, called for chemistry researchers to find solutions to aid in the manufacture of N fertilizers to help solve the coming food crisis.

In , Haber would be awarded the Nobel Prize in chemistry for his work in developing a method of synthesizing ammonia from nitrogen in the air—the process that enabled the production of fertilizer in quantities that revolutionized agriculture worldwide.

For his efforts directing a team of scientists on the front lines in World War I, he would become known as the father of chemical warfare. Elizabeth Classical School, where he took an early interest in chemistry. After studying at the University of Berlin, he transferred to the University of Heidelberg in and studied under the famed German chemist Robert Bunsen. Haber was ultimately appointed professor of physical chemistry and electrochemistry at the Karlshruhe Institute of Technology.

When scientists warned that the world would not be able to produce enough food to feed its growing human population in the 20th century, he listened. In , Haber married the brilliant chemist Clara Immerwahr, the first woman to receive a doctorate from Breslau University. Like Haber, she converted from Judaism to Christianity, and the couple settled in Karlsruhe.

To keep her mind stimulated, she began collaborating with her husband on a textbook on the thermodynamics of gas, and tried to continue her own research, writing and speaking.

Haber, unlike his friend Albert Einstein, was a German patriot, and he willingly became a uniformed consultant to the German War Office. Finding an effective delivery system was challenging—one test resulted in the deaths of several German troops. The Haber-Bosch process is generally credited with keeping Germany supplied with fertilizers and munitions during World War I, after the British naval blockade cut off supplies of nitrates from Chile.

During the war Haber threw his energies and those of his institute into further support for the German side. He developed a new weapon—poison gas, the first example of which was chlorine gas—and supervised its initial deployment on the Western Front at Ypres, Belgium, in His promotion of this frightening weapon precipitated the suicide of his wife, who was herself a chemist, and many others condemned him for his wartime role.

There was great consternation when he was awarded the Nobel Prize in Chemistry for for the synthesis of ammonia from its elements. After World War I, Haber was remarkably successful in building up his institute, but in the anti-Jewish decrees of the Nazi regime made his position untenable.

He retired a broken man, although at the time of his death he was on his way to investigate a possible senior research position in Rehovot in Palestine now Israel.



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